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Organic 2 Quiz Essay

521 words - 3 pages

Reaction Map of first semester organic reactions– Wiskur Spring 2012
HO

R X* R W* BrMg

X* W* Li R V* U* R or Cl) Br ( R I K H J G Y* F RO D Nuc R Br R R HO R OH V U R RO R L HO R

O Nuc R R Nuc X Br W R R M N Br R R H R O O H A* H Br R R Br (or Cl) OH Br O G* F* C* B* R O OH R D* H I* H* O R S* R O OH Br Y R Z J* R P* R* R R R R R L* R K* N* R M* Br R O* Br R O H T* Br Br R Br Q* Br Br R Br Br

O R O R S O O R

B A C

HO R

O P Q T S R HO R Br

A. LiAlH4 or NaBH4 (Chapter 12) B. PCC or KMnO4 or H2CrO4 (Chapter 12) C. RSO3Cl, ...view middle of the document...

H2/ Pd or H2/ Pt or H2/ Ni (Chapter 4) O. Br2 (Chapter 8) P. 1) BH3, 2) NaOH/ H2O2 (Chapter 8) Q. 1) O3, 2) CH3SCH3 (Chapter 8) R. HBr / peroxides (Chapter 10) S. Br2/H2O or chlorohydrin Cl2/H2O (Chapter 8) T. Br2, light (or heat) or NBS / light (or heat) (Chapter 10 notes/ Chapter 13 book) U. 1) OsO4, 2) NaHSO3 / H2O (Chapter 8) V. H2SO4/ROH (Chapter 8/11) W. NaOH, H2O (Chapter 11) X. Good nucleophile (Chapter 11) Y. Acid catalyzed – Nuc/ H2SO4 (Chapter 11) Z. Br2, light (or heat) A*. PBr3 or SOBr2, Et3N (Chapter 11) B*. KMnO4 or H2CrO4 (Chapter 12) C*. LiAlH4 (Chapter 12) D*. KMnO4 or H2CrO4 (Chapter 12) E*. Not on chart F*. PCC (Chapter 12) G*. NaBH4 or LiAlH4 (Chapter 12) H*. 2 equiv NaNH2 (Chapter 7)

I*. H2/ Pd/CaCO3 or H2/Ni2B orNa°/ NH3 (l) (Chapter 7) J*. H2/ Pd or H2/ Pt or H2/ Ni (Chapter 4) K*. H2/ Pd/CaCO3 or H2/Ni2B (Chapter 7) L*. Na°/ NH3 (l) (Chapter 7) M*. Hg(OAc)2/ H2SO4/ H2O or 1) BH3, 2) NaOH/ H2O2 (Chapter 8) N*. 1.) NaH, 2.) (RX primary) (Chapter 7) O*. Br2 (1 equiv) (Chapter 8) P*. HBr (Chapter 8) Q*. Br2 (excess) (Chapter 8) R*. 1) B(sia)2H, 2) NaOH/ H2O2 (Chapter 8) S*. Hg(OAc)2/ H2SO4/ H2O (Chapter 8) T*. HBr (Chapter 8) U*. Mg (metal), Et2O (Chapter 12) V*. Li (metal), Et2O (Chapter 12) W*. Acidic proton
O

X*. 1.) , 2.) dilute acid Y*. Conc. H2SO4/heat (Chapter 7)

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